The reaction shown above is a Baeyer-Villiger | vedclass

Name: Exam Paper Generator | JEE NEET Paper Generator | Vedclass
Brand: Vedclass
Rating: 5 (35 reviews)

Question

(A) The reaction is a Baeyer-Villiger oxidation of a ketone. In this rearrangement,an oxygen atom is inserted into the bond between the carbonyl carbo

Vedclass · Accepted Answer

Vedclass · Answer

(A) The reaction is a Baeyer-Villiger oxidation of a ketone. In this rearrangement,an oxygen atom is inserted into the bond between the carbonyl carbon and the more substituted alkyl group (migratory aptitude: tertiary alkyl > secondary alkyl > primary alkyl > methyl). For the given $2$-substituted cyclohexanone,the oxygen inserts between the carbonyl carbon and the more substituted carbon (the one bearing the $R$ group) to form a lactone. Thus,the product is the one where the oxygen is inserted between the carbonyl carbon and the carbon with the $R$ substituent,which corresponds to option $A$.

The reaction shown above is a Baeyer-Villiger rearrangement of an asymmetric ketone with magnesium monoperoxyphthalate hexahydrate (in the drawing,$Mg^{+2}$ is omitted for clarity). Identify the major product.

Similar Questions

The reaction between an ester and an excess of Grignard reagent $(R'MgX)$ finally results in a:

Which of the following reacts with $2,4-DNP$ reagent to give an orange precipitate?

Which of the following compounds will react with water?

Acetaldehyde and Acetone can be distinguished by

Of the following,which is the product formed when cyclohexanone undergoes aldol condensation followed by heating?

Vedclass Test Series

Exam Paper Generator

Online Exam Module